Effects of the tetravanadate [V₄O₁₂]^4- anion on the structural, magnetic, and biological properties of copper/phenanthroline complexes.

ABSTRACT: The aim to access linked tetravanadate [V₄O₁₂]^4- anion with mixed copper(II) complexes, using α-amino acids and phenanthroline-derived ligands, resulted in the formation of four copper(II) complexes [Cu(dmb)(Gly)(OH₂)]₂[Cu(dmb)(Gly)]₂[V₄O₁₂]·9H₂O (1) [Cu(dmb)(Lys)]₂[V₄O₁₂]·8H₂O (2), [Cu(dmp)₂][V₄O₁₂]·C₂H₅OH·11H₂O (3), and [Cu(dmp)(Gly)Cl]·2H₂O (4), where dmb = 4,4'-dimethioxy-2,2'-bipyridine; Gly = glycine; Lys = lysine; and dmp = 2,9-dimethyl-1,10-phenanthroline. The [V₄O₁₂]^4- anion is functionalized with mixed copper(II) units in 1 and 2;

SUBMITTER: Sanchez-Lara E 

PROVIDER: S-EPMC11001746 | biostudies-literature | 2024 Feb

REPOSITORIES: biostudies-literature