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Enhanced hydrogen uptake of dihydrogen complex via porous materials support.

ABSTRACT: This research focuses on enhancing H₂ adsorption by using the [Mo(PCy₃)₂(CO)₃] complex supported on porous materials such as silica gel and mesoporous carbon. The study reports a significant increase in hydrogen adsorption capacity, reaching up to 9.3 times that of the bulk complex. This improvement suggests that using mesoporous materials as supports for the [Mo(PCy₃)₂(CO)₃] complex enhances the accessibility of H₂ gas to its open-metal sites.

SUBMITTER: Uchida K

PROVIDER: S-EPMC11003236 | biostudies-literature | 2024 Apr

REPOSITORIES: biostudies-literature

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Enhanced hydrogen uptake of dihydrogen complex via porous materials support.

Uchida Kaiji K Tanaka Shunya S Adachi Shuta S Iguchi Hiroaki H Sakamoto Ryota R Takaishi Shinya S

RSC advances 20240409 16

This research focuses on enhancing H2 adsorption by using the [Mo(PCy3)2(CO)3] complex supported on porous materials such as silica gel and mesoporous carbon. The study reports a significant increase in hydrogen adsorption capacity, reaching up to 9.3 times that of the bulk complex. This improvement suggests that using mesoporous materials as supports for the [Mo(PCy3)2(CO)3] complex enhances the accessibility of H ...[more]

PMID: 38595716

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