Direct Oxidation of Methane to Methanol over Transition-Metal-Free Ferrierite Zeolite Catalysts.

ABSTRACT: Direct oxidation of methane to methanol was reported to be highly dependent on the transition- or noble-metal-loading catalysts in the past decades. Here, we show that the transition-metal-free aluminosilicate ferrierite (FER) zeolite effectively catalyzed methane and N₂O to methanol for the first time. The distorted tetracoordinated Al in the framework and pentacoordinated Al on the extra framework formed during calcination, activation, and reaction processes were confirmed as the potential active centers. The possible reaction pathway similar to the Fe-containing zeolites was advocated based on the reaction results using different oxidants, N₂O adsorption FTIR spectra, and ²⁷Al MAS NMR spectra. The stable and efficient methanol production capacity of FER

SUBMITTER: Xiao P 

PROVIDER: S-EPMC11009945 | biostudies-literature | 2024 Apr

REPOSITORIES: biostudies-literature