Loading of Single Atoms of Iron, Cobalt, or Nickel to Enhance the Electrocatalytic Hydrogen Evolution Reaction of Two-Dimensional Titanium Carbide.

ABSTRACT: The rational design of advanced electrocatalysts at the molecular or atomic level is important for improving the performance of hydrogen evolution reactions (HERs) and replacing precious metal catalysts. In this study, we describe the fabrication of electrocatalysts based on Fe, Co, or Ni single atoms supported on titanium carbide (TiC) using the molten salt method, i.e., TiC-Fe_SA, TiC-Co_SA, or TiC-Ni_SA, to enhance HER performance. The introduction of uniformly distributed transition-metal single atoms successfully reduces the overpotential of HERs. Overpotentials of TiC-Fe_SA at 10 mA cm^-2 are 123.4 mV with 61.1 mV dec^-1 Tafel slope under acidic conditions and 184.2 mV with 85.1 mV dec^-1 Tafel slope under alkaline

SUBMITTER: Wang K 

PROVIDER: S-EPMC11012987 | biostudies-literature | 2024 Apr

REPOSITORIES: biostudies-literature