Variation in the relationship between odd isotopes of tin in mass-independent fractionation induced by the magnetic isotope effect.

ABSTRACT: Experimental results are presented showing the variation in the relationship between odd isotopes of tin (Sn) in mass-independent fractionation caused by the magnetic isotope effect (MIE), which has previously only been observed for mercury. These results are consistent with the trend predicted from the difference between the magnitudes of nuclear magnetic moments of odd isotopes with a nuclear spin. However, the correlation between odd isotopes in fractionation induced by the MIE for the reaction system used in this study (solvent extraction using a crown ether) was different from that reported for the photochemical reaction of methyltin. This difference between the two reaction systems is consistent with a theoretical prediction that the correlation between odd isotopes in fractionation

SUBMITTER: Fukami Y 

PROVIDER: S-EPMC11046578 | biostudies-literature | 2024 Apr

REPOSITORIES: biostudies-literature