Composition effects of electrodeposited Cu-Ag nanostructured electrocatalysts for CO₂ reduction.

ABSTRACT: The electrochemical carbon dioxide reduction (CO₂RR) on Cu-based catalysts is a promising strategy to store renewable electricity and produce valuable C₂₊ chemicals. We investigate the CO₂RR on Cu-Ag nanostructures that have been electrodeposited in a green choline chloride and urea deep eutectic solvent (DES). We determine the electrochemically active surface area (ECSA) using lead underpotential deposition (UPD) to investigate the CO₂RR intrinsic activity and selectivity. We show that the addition of Ag on electrodeposited Cu primarily suppresses the production of hydrogen and methane. While the production of carbon monoxide slightly increases, the partial current of the total C₂₊ products does not considerably increase. Despite that

SUBMITTER: Plaza-Mayoral E 

PROVIDER: S-EPMC11134916 | biostudies-literature | 2024 Jun

REPOSITORIES: biostudies-literature