Synthesis, Characterization, and Catalytic Performance of a New Heterobimetallic Y/Tb Metal-Organic Framework with High Catalytic Activity.

ABSTRACT: A three-dimensional heterobimetallic porous structure with the formula {[Y_3.5Tb_1.5L₆(OH)₃(H₂O)_1.5 (DMF)_1.5] _n ·1.5H₂O·DMF} _n (L = 3-amino-4-hydroxybenzoate) (Y/Tb-MOF) has been synthesized and characterized by single crystal and powder X-ray diffraction, scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX), inductively coupled plasma mass spectrometry (ICP-MS), electrophoretic mobility, and Fourier transform infrared (FTIR) spectroscopy. The structure presents two metal environments: a bioaugmented isosceles wedge (mm2) MO₈ and a tricapped trigonal prism (-6m2) MN₃O₆. These configurations facilitate t

SUBMITTER: Lopez-Vargas ME 

PROVIDER: S-EPMC11191568 | biostudies-literature | 2024 Jun

REPOSITORIES: biostudies-literature