Selective Adsorption of Sr(II) from Aqueous Solution by Na3FePO4CO3: Experimental and DFT Studies
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PROVIDER: S-EPMC11206743 | biostudies-literature | 2024 Jun
REPOSITORIES: biostudies-literature
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Project description:Microwave-ultrasound-assisted facile synthesis of a dumbbell- and flower-shaped potato starch phosphate (PSP) polymer, hereafter PSP, was carried out by cross-linking the hydroxyl groups of native potato starch (NPS) using phosphoryl chloride as a cross-linking agent. Structural and morphological analysis manifested the successful formation of the dumbbell- and flower-shaped PSP biosorbent with enhanced specific surface area and thermal stability. Viscoelastic behavior of NPS and PSP suggested increased rigidity in PSP, which helped the material to store more deformation energy in an elastic manner. The synthesized PSP biosorbent material was successfully tested for efficient and quick uptake of Zn(II), Pb(II), Cd(II), and Hg(II) ions from aqueous medium under competitive and noncompetitive batch conditions with q m values of 130.54, 106.25, 91.84, and 51.38 mg g-1, respectively. The adsorption selectivity was in consonance with Pearson's hard and soft acids and bases (HSAB) theory in addition to their order of hydrated radius. Adsorption of Zn(II), Pb(II), Cd(II), and Hg(II) followed a second-order kinetics and the adsorption data fitted well with the Langmuir isotherm model. Quantum computations using density functional theory (DFT) further supported the experimental adsorption selectivity, Zn(II) > Pb(II) > Cd(II) > Hg(II), in terms of metal-oxygen binding energy measurements. What was more intriguing about PSP was its reusability over multiple adsorption cycles by treating the metal(II)-complexed PSP with 0.1 M HCl without any appreciable loss of its adsorption capacity.
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Project description:In this work, we report the synthesis of two Schiff bases of substituted gallic acid derivatives via amidation reaction and their characterization using 1H-NMR spectroscopy to study their inhibition performance on the aggressive attack of HCl on mild steel (MS). The inhibitive performance was examined using chemical (weight loss) and electrochemical (Tafel and EIS) test methods. The results indicate that these derivatives significantly suppress the dissolution rate of mild steel via adsorption phenomena, which correlates to the Langmuir adsorption model. Tafel data display the mixed-type properties of these compounds and EIS results show that increasing Schiff base concentration not only leads to delaying the charge transfer (R ct) of iron from 26.4 ohm cm-2 to 227.7 ohm cm-2 but also decreases the capacitance of the adsorbed double layer (C dl) from 8.58 (F cm-2) × 10-5 to 2.55 (F cm-2) × 10-5. The inhibition efficiency percentage reaches the peak (90%) at optimum concentration of 250 ppm. The Monte Carlo simulations confirm the adsorption ability of the as-prepared compounds on the Fe (1 1 0) crystal. The SEM/EDX results revealed the presence of a protective film on the mild steel sample.
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