Open-Cage Copper Complexes Modulate Coordination and Charge Transfer.

ABSTRACT: This study presents a novel copper-based redox shuttle that employs the PY5 pentadentate polypyridyl ligand in a dye-sensitized solar cell (DSSC). The [Cu(PY5)]²⁺ complex exhibits a unique five-coordinate square pyramidal geometry, characterized by a strategically labile axial position, to facilitate efficient dye regeneration while minimizing electron recombination, thereby enhancing DSSC performance. Notably, the inclusion of 4-tert-butylpyridine (TBP) as an additive is shown to significantly modulate the electrochemical and photophysical properties of the copper complexes, attributed to its coordination to the vacant axial site. This interaction leads to an improved open-circuit voltage and overall device efficiency, with the complexes achieving promising efficiencies

SUBMITTER: Firestone E 

PROVIDER: S-EPMC11220750 | biostudies-literature | 2024 Jul

REPOSITORIES: biostudies-literature