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The crystal structure of the ammonium salt of 2-aminomalonic acid.


ABSTRACT: The salt ammonium 2-aminomalonate (systematic name: ammonium 2-azaniumylpropanedioate), NH4+·C3H4NO4-, was synthesized in diethyl ether from the starting materials malonic acid, ammonia and bromine. The salt was recrystallized from water as colourless blocks. In the solid state, intramolecular medium-strong N-H...O, weak C-H...O and weak C-H...N hydrogen bonds build a three-dimensional network.

SUBMITTER: Hollenwager D 

PROVIDER: S-EPMC11225614 | biostudies-literature | 2024 Jul

REPOSITORIES: biostudies-literature

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The crystal structure of the ammonium salt of 2-aminomalonic acid.

Hollenwäger Dirk D   Nitzer Alexander A   Bockmair Valentin V   Kornath Andreas J AJ  

Acta crystallographica. Section C, Structural chemistry 20240619 Pt 7


The salt ammonium 2-aminomalonate (systematic name: ammonium 2-azaniumylpropanedioate), NH<sub>4</sub><sup>+</sup>·C<sub>3</sub>H<sub>4</sub>NO<sub>4</sub><sup>-</sup>, was synthesized in diethyl ether from the starting materials malonic acid, ammonia and bromine. The salt was recrystallized from water as colourless blocks. In the solid state, intramolecular medium-strong N-H...O, weak C-H...O and weak C-H...N hydrogen bonds build a three-dimensional network. ...[more]

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