Hierarchically porous and single Zn atom-embedded carbon molecular sieves for H₂ separations.

ABSTRACT: Hierarchically porous materials containing sub-nm ultramicropores with molecular sieving abilities and microcavities with high gas diffusivity may realize energy-efficient membranes for gas separations. However, rationally designing and constructing such pores into large-area membranes enabling efficient H₂ separations remains challenging. Here, we report the synthesis and utilization of hybrid carbon molecular sieve membranes with well-controlled nano- and micro-pores and single zinc atoms and clusters well-dispersed inside the nanopores via the carbonization of supramolecular mixed matrix materials containing amorphous and crystalline zeolitic imidazolate frameworks. Carbonization temperature is used to fine-tune pore sizes, achieving ultrahigh selectivity for H₂/CO

SUBMITTER: Hu L 

PROVIDER: S-EPMC11227577 | biostudies-literature | 2024 Jul

REPOSITORIES: biostudies-literature