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Achieving High Dispersion of Pd in Small-Pore Zeolite SSZ-13: A High-Efficiency Low-Temperature NOx Adsorber.


ABSTRACT: Passive NO x adsorber (PNA) materials are primarily considered for reducing nitrogen oxide emissions during the low-temperature cold start of a motor vehicle. Pd/SSZ-13 has attracted considerable attention because of its outstanding hydrothermal stability and sulfur resistance. Optimizing the dispersion of precious metal Pd in Pd/SSZ-13 is crucial for enhancing PNA performance and nitrogen oxide adsorption capability. In this study, we prepared Pd/SSZ-13 using different methods and evaluated their influence on the NO x adsorption capability. The characterization results show that the dispersion of precious metal Pd in the Pd/SSZ-13 catalyst prepared by the quantitative ion-exchange method is as high as 92.13%, and the loading amount is as high as 98.93%.

SUBMITTER: Liu Y 

PROVIDER: S-EPMC11256304 | biostudies-literature | 2024 Jul

REPOSITORIES: biostudies-literature