Co-Cation Engineering via Mixing of Acetamidinium and Rubidium in FASnI₃ for Tin Perovskite Solar Cells to Attain 14.5% Efficiency.

ABSTRACT: Tin perovskite solar cells (TPSCs) were developed by adding the co-cations acetamidinium (AC) and rubidium (Rb) in varied proportions based on the FASnI₃ structure (E1). We found that adding 10% AC and 3% Rb can optimize the device (E1AC10Rb3) to attain an efficiency of power conversion of 14.5% with great shelf- and light-soaking stability. The films at varied AC and Rb proportions were characterized using XPS, SEM, AFM, GIWAXS, XRD, TOPAS, TOF-SIMS, UV-vis, PL, TCSPC, and femtosecond TAS techniques to show the excellent optoelectronic properties of the E1AC10Rb3 film in comparison to those of the other films. AC was found to have the effect of passivating the vacancy defects on the surface and near the bottom of the film, while Rb plays a pivotal role in passivating the bottom

SUBMITTER: Kuan CH 

PROVIDER: S-EPMC11299185 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature