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Surface engineering of high-k polymeric dielectric layers with a fluorinated organic crosslinker for use in flexible-platform electronics.


ABSTRACT: High-k polymeric layers were prepared by combining various functional groups and were applied as gate dielectrics for practical organic field-effect transistors (OFETs). Crosslinking of the polymeric layers through UV-assisted organic azide fluorine-based crosslinkers induced dramatic improvements in the electrical performance of the OFET, such as field-effect mobility and bias-stress stability. Our synthesis and manufacturing method can be a useful technique for ensuring device operation stability and electrical property enhancement. With this analysis, we further applied our polymer-dielectric OFETs to flexible-platform-based electronic components, including unit OFETs and simple logic devices (NOT, NAND, and NOR gates). The outcomes of this research and development suggest a suitable method for the low-cost mass production of large-area flexible and printable devices, using a printing-based approach to replace current processes.

SUBMITTER: Ye H 

PROVIDER: S-EPMC11302166 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature

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Surface engineering of high-<i>k</i> polymeric dielectric layers with a fluorinated organic crosslinker for use in flexible-platform electronics.

Ye Heqing H   Kwon Hyeok-Jin HJ   Ryu Ka Yeon KY   Wu Kaibin K   Park Jeongwan J   Babita Giri G   Kim Inae I   Yang Chanwoo C   Kong Hoyoul H   Kim Se Hyun SH  

Nanoscale advances 20240627 16


High-<i>k</i> polymeric layers were prepared by combining various functional groups and were applied as gate dielectrics for practical organic field-effect transistors (OFETs). Crosslinking of the polymeric layers through UV-assisted organic azide fluorine-based crosslinkers induced dramatic improvements in the electrical performance of the OFET, such as field-effect mobility and bias-stress stability. Our synthesis and manufacturing method can be a useful technique for ensuring device operation  ...[more]

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