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A cobalt-modified covalent organic framework enables highly efficient degradation of 2,4-dichlorophenol in high concentrations through peroxymonosulfate activation.

ABSTRACT: The development of covalent organic frameworks (COFs) which can rapidly degrade high concentrations of 2,4-dichlorophenol is of great significance for its practical application. In this work, we report a cobalt-doped two-dimensional (2D) COF (JLNU-307-Co) for the ultra-efficient degradation of high concentration 2,4-dichlorophenol (2,4-DCP) by activating peroxymonosulfate (PMS). The JLNU-307-Co/PMS system takes only 3 min to degrade 100% of 50 mg L^-1 2,4-DCP and shows excellent catalytic stability in real water. The superoxide radical (O₂˙^-) and singlet oxygen (¹O₂) play a major role in the system through capture experiments and electron spin resonance (ESR) tests. Compared to most previously reported catalysts, JLNU-307-Co/PMS showed the highest efficiency to date in degrading 2,4-DCP. This work not only demonstrates the potential of COFs as a catalyst for water environmental treatment, but also provides unprecedented insights into the degradation of organic pollutants.

SUBMITTER: Ma Y

PROVIDER: S-EPMC11304524 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature

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A cobalt-modified covalent organic framework enables highly efficient degradation of 2,4-dichlorophenol in high concentrations through peroxymonosulfate activation.

Ma Yunchao Y Han Yuhang Y Yao Yuxin Y Zhou Tianyu T Sun Dongshu D Liu Chunbo C Che Guangbo G Hu Bo B Valtchev Valentin V Fang Qianrong Q

Chemical science 20240702 31

The development of covalent organic frameworks (COFs) which can rapidly degrade high concentrations of 2,4-dichlorophenol is of great significance for its practical application. In this work, we report a cobalt-doped two-dimensional (2D) COF (JLNU-307-Co) for the ultra-efficient degradation of high concentration 2,4-dichlorophenol (2,4-DCP) by activating peroxymonosulfate (PMS). The JLNU-307-Co/PMS system takes only 3 min to degrade 100% of 50 mg L<sup>-1</sup> 2,4-DCP and shows excellent cataly ...[more]

PMID: 39118632

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Project description:Background2,4-Dichlorophenol (2,4-DCP), 2,5-dichlorophenol (2,5-DCP), and their precursors are widely used in industry and in consumer products. Urinary concentrations of these dichlorophenols (DCPs) have been measured as part of four National Health and Nutrition Examination Survey (NHANES) cycles in order to assess the exposure to these compounds or their precursors among the general U.S. population.ObjectivesWe identified predictors and evaluated trends in DCP concentrations according to race/ethnicity, age, sex, family income, and housing type.MethodsWe used analysis of covariance to examine associations of various demographic parameters and survey cycle with urinary concentrations of DCPs during NHANES 2003-2010. We also conducted weighted logistic regressions to estimate associations of DCP concentrations above the 95th percentile with housing type, race/ethnicity, and income.ResultsWe detected DCPs in at least 81% of participants. Geometric mean (GM) urinary concentrations were higher for 2,5-DCP (6.1-12.9 μg/L) than 2,4-DCP (0.8-1.0 μg/L) throughout 2003-2010. Adjusted GM concentrations of the DCPs among children (6-11 years of age) and adults > 60 years of age were higher than among adolescents and other adults. Adjusted GM concentrations among non-Hispanic whites were lower than among non-Hispanic blacks and Mexican Americans, although differences according to race/ethnicity were less pronounced among participants in high-income households. Among non-Hispanic blacks and Mexican Americans, adjusted GM concentrations were lowest among high-income participants relative to other income groups, with a monotonic decrease with increasing income among Mexican Americans. Type of housing and race/ethnicity were significant predictors of DCP urinary concentrations above the 95th percentile. Furthermore, urinary DCP concentrations have showed a downward trend since 2003.ConclusionsExposure to DCPs and their precursors was prevalent in the general U.S. population in 2003-2010. We identified age and race/ethnicity, family income, and housing type as predictors of exposure to these compounds.

Dataset Information

A cobalt-modified covalent organic framework enables highly efficient degradation of 2,4-dichlorophenol in high concentrations through peroxymonosulfate activation.

Publications

A cobalt-modified covalent organic framework enables highly efficient degradation of 2,4-dichlorophenol in high concentrations through peroxymonosulfate activation.

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