High-entropy superparaelectrics with locally diverse ferroic distortion for high-capacitive energy storage.

ABSTRACT: Superparaelectrics are considered promising candidate materials for achieving superior energy storage capabilities. However, due to the complicated local structural design, simultaneously achieving high recoverable energy density (W_rec) and energy storage efficiency (η) under high electric fields remains a challenge in bulk superparaelectrics. Here, we propose utilizing entropy engineering to disrupt long-range ferroic orders into local polymorphic distortion disorder with multiple BO₆ tilt types and diverse heterogeneous polarization configurations. This strategy reduces the switching barriers, thereby facilitating the emergence of superparaelectric behaviors with ideal polarization forms. Furthermore, it enables high polarization response, negligible remnant polariz

SUBMITTER: Duan J 

PROVIDER: S-EPMC11310198 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature