Phospha-bicyclohexene-germylenes exhibiting unexpected reactivity.

ABSTRACT: Introducing phospha-bicyclohexene (BCH)-germylenes (BCHGe's) as a novel, multifunctional compound class: the title compounds 15-18 are obtained from simple salt metathesis reactions of dipotassium germacyclopentadienediides K₂[1] with phosphorusdichlorides. The BCHGe's 15-18 are stabilized by homoconjugation of the germanium(ii) centre with the remote C[double bond, length as m-dash]C double bond. Despite substantial thermodynamic stabilization, phospha-BCHGe's are reactive and undergo a reductive elimination of elemental germanium to give the corresponding phospholes. The elimination is a nucleophilic, bimolecular process and is prevented by large substituents. The reaction of phospha-BCHGe's with small electrophiles gives the corresponding phosphonium salts. Oxidation with cha

SUBMITTER: Wurdemann MS 

PROVIDER: S-EPMC11310892 | biostudies-literature | 2024 Jul

REPOSITORIES: biostudies-literature