Bioinspired Binding and Conversion of Linear Monoterpenes by Polyaromatic Coordination Capsules.

ABSTRACT: Linear monoterpenes, versatile reaction biosubstrates, are bound and subsequently converted to various cyclic monomers and oligomers with excellent selectivity and efficiency, only in natural enzymes. We herein report bioinspired functions of synthetic polyaromatic cavities toward linear monoterpenes in the solution and solid states. The cavities are provided by polyaromatic coordination capsules, formed by the assembly of Pt(II) ions and bent bispyridine ligands with two anthracene panels. By using the capsule cavities, the selective binding of citronellal from mixtures with other monoterpenes and its preferential vapor binding over its derivatives are demonstrated in water and in the solid state, respectively. The capsule furthermore extracts p-menthane-3,8-diol, with high

SUBMITTER: Sumida R 

PROVIDER: S-EPMC11311458 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature