Rescue of dead MnO₂ for stable electrolytic Zn-Mn redox-flow battery: a metric of mediated and catalytic kinetics.

ABSTRACT: The virtues of electrolytic MnO₂ aqueous batteries are high theoretical energy density, affordability and safety. However, the continuous dead MnO₂ and unstable Mn²⁺/MnO₂ electrolysis pose challenges to the practical output energy and lifespan. Herein, we demonstrate bifunctional cationic redox mediation and catalysis kinetics metrics to rescue dead MnO₂ and construct a stable and fast electrolytic Zn-Mn redox-flow battery (eZMRFB). Spectroscopic characterizations and electrochemical evaluation reveal the superior mediation kinetics of a cationic Fe²⁺ redox mediator compared with the anionic ones (e.g. I^- and Br^-), thus eliminating dead MnO₂ effectively. With intensified oxygen vacancies, den

SUBMITTER: Wang Q 

PROVIDER: S-EPMC11312367 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature