On the origin of low-valent uranium oxidation state.

ABSTRACT: The significant interest in actinide bonding has recently focused on novel compounds with exotic oxidation states. However, the difficulty in obtaining relevant high-quality experimental data, particularly for low-valent actinide compounds, prevents a deeper understanding of 5f systems. Here we show X-ray absorption near-edge structure (XANES) measurements in the high-energy resolution fluorescence detection (HERFD) mode at the uranium M₄ edge for the U^III and U^IV halides, namely UX₃ and UX₄ (X = F, Cl, Br, I). The spectral shapes of these two series exhibit clear differences, which we explain using electronic structure calculations of the 3d-4f resonant inelastic X-ray scattering (RIXS) process. To understand the changes observed, we

SUBMITTER: Silva CL 

PROVIDER: S-EPMC11316815 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature