Adjusting UV-Vis Spectrum of Alizarin by Insertion of Auxochromes.

ABSTRACT: First synthesized in 1868, alizarin became one of the first synthetic dyes and was widely used as a red dye in the textile industry, making it more affordable and readily available than the traditional red dyes derived from natural sources. Despite extensive both experimental and computational analyses on the electronic effects of substituents on the shape of the visible spectrum of alizarin and alizarin Red S, no previous systematic work has been undertaken with the aim to fine tune the dominant absorption region defining its color by introducing other electron-withdrawing or electron-donor groups. For such, we have performed a comprehensive study of electronic effects of substituents in position C₃ of alizarin by means of a time dependent DFT approach. These auxochromes attach

SUBMITTER: Noori Z 

PROVIDER: S-EPMC11319224 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature