Aromatic 2,2-Diphenylethylamine Ligand Exchange of FA0.9Cs0.1PbBr3 Perovskite Nanocrystals for High-Efficiency Pure Green Light-Emitting Diodes.

ABSTRACT: Perovskite nanocrystals (NCs) with long alkyl ligands cannot easily form high-quality composite films owing to their poor dispersibility in π-conjugated small molecules and polymer host materials. In this study, we demonstrated that the aromatic ligand exchange of mixed-cation FA0.9Cs0.1PbBr3 NCs using 2,2-diphenylethylamine (DPEA) can not only enable the fabrication of high-efficiency light-emitting diodes (LEDs) but also allows dispersibility in host materials. The DPEA-NC film exhibited a pure green wavelength of 530 nm and a full width at half-maximum of 20.9 nm with a photoluminescence quantum yield of 90.9%. A DPEA-NC LED achieved a luminance of 39,700 cd/m2 and an external quantum efficiency of 18.6% even in a thick NC film. Interestingly, the DPEA-NCs formed a composite film with s

SUBMITTER: Mizoguchi S 

PROVIDER: S-EPMC11325396 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature