Proton Conduction in Chiral Molecular Assemblies of Azolium-Camphorsulfonate Salts.

ABSTRACT: Chiral molecular assemblies have attracted considerable attention because of their interesting physical properties, such as spin-selective electron transport. Cation-anion salts of three azolium cations, imidazolium (HIm⁺), triazolium (HTrz⁺), and thiazolium (HThz⁺), in combination with a chiral camphorsulfonate (1S-CS^-) and their racemic compounds (rac-CS^-) were prepared and compared in terms of phase transitions, crystal structures, dynamics of constituent molecules, dielectric responses, and proton conductivities. The cation-anion crystals containing HIm⁺ showed no significant difference in proton conductivity between the hom

SUBMITTER: Sato C 

PROVIDER: S-EPMC11328138 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature