Trace element detection in anhydrous minerals by micro-scale quantitative nuclear magnetic resonance spectroscopy.

ABSTRACT: Nominally anhydrous minerals (NAMs) composing Earth's and planetary rocks incorporate microscopic amounts of volatiles. However, volatile distribution in NAMs and their effect on physical properties of rocks remain controversial. Thus, constraining trace volatile concentrations in NAMs is tantamount to our understanding of the evolution of rocky planets and planetesimals. Here, we present an approach of trace-element quantification using micro-scale Nuclear Magnetic Resonance (NMR) spectroscopy. This approach employs the principle of enhanced mass-sensitivity in NMR microcoils. We were able to demonstrate that this method is in excellent agreement with standard methods across their respective detection capabilities. We show that by simultaneous detection of internal reference nuclei, the q

SUBMITTER: Fu Y 

PROVIDER: S-EPMC11344839 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature