Perfluoroalkyl functionalized-Au nanoparticle sensor: Employing rate of spectrum shifting for highly selective and sensitive detection of per- and polyfluoroalkyl substances (PFASs) in aqueous environments.

ABSTRACT: Per- and polyfluoroalkyl substances (PFASs) are emerging contaminants detected ubiquitously and have negative impacts on human health and ecosystem; thus, developing in-situ sensing technique is important to ensure safety. Herein, we report a novel colorimetric-based sensor with perfluoroalkyl receptor attached to citrate coated gold nanoparticles (Citrate-Au NPs) that can detect several PFASs including perfluorocarboxylates with different chain lengths (PFHxA, PFOA, PFNA, PFDA), perfluorooctanoic sulfonate (PFOS), and perfluorooctanoic phosphonate (PFOPA). The sensor detects PFASs utilizing fluorous interaction between PFASs and the perfluoroalkyl receptor of Citrate-Au NPs in a solution at a fixed salt concentration, inducing changes in nanoparticle dispersity and the solution col

SUBMITTER: Jung J 

PROVIDER: S-EPMC11347827 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature