Extensive hydrogen incorporation is not necessary for superconductivity in topotactically reduced nickelates.

ABSTRACT: A key open question in the study of layered superconducting nickelate films is the role that hydrogen incorporation into the lattice plays in the appearance of the superconducting state. Due to the challenges of stabilizing highly crystalline square planar nickelate films, films are prepared by the deposition of a more stable parent compound which is then transformed into the target phase via a topotactic reaction with a strongly reducing agent such as CaH₂. Recent studies, both experimental and theoretical, have introduced the possibility that the incorporation of hydrogen from the reducing agent into the nickelate lattice may be critical for the superconductivity. In this work, we use secondary ion mass spectrometry to examine superconducting La_1-xX_xNiO

SUBMITTER: Balakrishnan PP 

PROVIDER: S-EPMC11349950 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature