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Nitrogen-Tungsten Oxide Nanostructures on Nickel Foam as High Efficient Electrocatalysts for Benzyl Alcohol Oxidation.

ABSTRACT: Electrocatalytic alcohol oxidation (EAO) is an attractive alternative to the sluggish oxygen evolution reaction in electrochemical hydrogen evolution cells. However, the development of high-performance bifunctional electrocatalysts is a major challenge. Herein, we developed a nitrogen-doped bimetallic oxide electrocatalyst (WO-N/NF) by a one-step hydrothermal method for the selective electrooxidation of benzyl alcohol to benzoic acid in alkaline electrolytes. The WO-N/NF electrode features block-shaped particles on a rough, inhomogeneous surface with cracks and lumpy nodules, increasing active sites and enhancing electrolyte diffusion. The electrode demonstrates exceptional activity, stability, and selectivity, achieving efficient benzoic acid production while reducing the electrolysis voltage. A low onset potential of 1.38 V (vs. RHE) is achieved to reach a current density of 100 mA cm^-2 in 1.0 M KOH electrolyte with only 0.2 mmol of metal precursors, which is 396 mV lower than that of water oxidation. The analysis reveals a yield, conversion, and selectivity of 98.41%, 99.66%, and 99.74%, respectively, with a Faradaic efficiency of 98.77%. This work provides insight into the rational design of a highly active and selective catalyst for electrocatalytic alcohol oxidation.

SUBMITTER: Zhu Y

PROVIDER: S-EPMC11357156 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature

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Nitrogen-Tungsten Oxide Nanostructures on Nickel Foam as High Efficient Electrocatalysts for Benzyl Alcohol Oxidation.

Zhu Yizhen Y Chen Xiangyu X Zhang Yuanyao Y Zhu Zhifei Z Chen Handan H Chai Kejie K Xu Weiming W

Molecules (Basel, Switzerland) 20240807 16

Electrocatalytic alcohol oxidation (EAO) is an attractive alternative to the sluggish oxygen evolution reaction in electrochemical hydrogen evolution cells. However, the development of high-performance bifunctional electrocatalysts is a major challenge. Herein, we developed a nitrogen-doped bimetallic oxide electrocatalyst (WO-N/NF) by a one-step hydrothermal method for the selective electrooxidation of benzyl alcohol to benzoic acid in alkaline electrolytes. The WO-N/NF electrode features block ...[more]

PMID: 39202814

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Project description:The security of future energy, hydrogen, is subject to designing high-performance, stable, and low-cost electrocatalysts for hydrogen and oxygen evolution reactions (HERs and OERs), for the realization of efficient overall water splitting. Two-dimensional (2D) metal-organic frameworks (MOFs) introduce a large family of materials with versatile chemical and structural features for a variety of applications, such as supercapacitors, gas storage, and water splitting. Herein, a series of nanocomposites based on NCM/Ni-BDC@NF (N=Ni, C=Co, M:F=Fe, C=Cu, and Z=Zn, BDC: benzene dicarboxylic acid, NF: nickel foam) were directly developed on NF using a facile yet scalable solvothermal method. After coupling, the electronic structure of metallic atoms was well-modulated. Based on the XPS results, for the NCF/Ni-BDC, cationic atoms shifted to higher oxidation states, favorable for the OER. Conversely, for the NCZ/Ni-BDC and NCC/Ni-BDC nanocomposites, cationic atoms shifted to lower oxidation states, advantageous for the HER. The as-prepared NCF/Ni-BDC demonstrated prominent OER performance, requiring only 1.35 and 1.68 V versus a reversible hydrogen electrode to afford 10 and 50 mA cm-2 current densities, respectively. On the cathodic side, NCZ/Ni-BDC exhibited the best HER activity with an overpotential of 170 and 350 mV to generate 10 and 50 mA cm-2, respectively, under 1.0 M KOH medium. In a two-electrode alkaline electrolyzer, the assembled NCZ/Ni-BDC (cathode) ∥ NCF/Ni-BDC (anode) couple demanded a cell voltage of only 1.58 V to produce 10 mA cm-2. The stability of NCF/Ni-BDC toward OER was also exemplary, experiencing a continuous operation at 10, 20, and 50 mA cm-2 for nearly 45 h. Surprisingly, the overpotential after OER stability at 50 mA cm-2 dropped drastically from 450 to 200 mV. Finally, the faradaic efficiencies for the overall water splitting revealed the respective values of 100 and 85% for the H2 and O2 production at a constant current density of 20 mA cm-2.

Dataset Information

Nitrogen-Tungsten Oxide Nanostructures on Nickel Foam as High Efficient Electrocatalysts for Benzyl Alcohol Oxidation.

Publications

Nitrogen-Tungsten Oxide Nanostructures on Nickel Foam as High Efficient Electrocatalysts for Benzyl Alcohol Oxidation.

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