Revealing the Local Structure and Dynamics of the Solid Li Ion Conductor Li₃P₅O₁₄.

ABSTRACT: The development of fast Li ion-conducting materials for use as solid electrolytes that provide sufficient electrochemical stability against electrode materials is paramount for the future of all-solid-state batteries. Advances on these fast ionic materials are dependent on building structure-ionic mobility-function relationships. Here, we exploit a series of multinuclear and multidimensional nuclear magnetic resonance (NMR) approaches, including ⁶Li and ³¹P magic angle spinning (MAS), in conjunction with density functional theory (DFT) to provide a detailed understanding of the local structure of the ultraphosphate Li₃P₅O₁₄, a promising candidate for an oxide-based Li ion conductor that has been shown to be a highly conductive, energet

SUBMITTER: Duff BB 

PROVIDER: S-EPMC11360135 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature