Hydrothermal synthesis, structures, and catalytic performance of five coordination compounds driven by 5-aminoisophthalic acid.

ABSTRACT: An amino-functionalized-dicarboxylic acid, 5-aminoisophthalic acid (H₂aipa), was used as a versatile building block to synthesize a series of five novel coordination compounds under hydrothermal conditions and formulated as [Co(μ₃-aipa)(2,2'-H₂biim)] _n (1), [Ni₂(μ-aipa)₂(2,2'-H₂biim)₂(H₂O)₄]·4H₂O (2), {[Cd(μ₃-aipa)(2,2'-H₂biim)]·H₂O} _n (3), {[Ni(μ-aipa)(μ-bpb)]·0.5bpb·H₂O} _n (4), and {[Ni₂(μ-aipa)(μ₃-aipa)(μ-dpea)₂(H₂O)][Ni(μ-aipa)(μ-dpea)(H₂O)]·8H₂O} _n (5). Three supporting ligands (2,2'-biimidazole (H

SUBMITTER: Mei ZZ 

PROVIDER: S-EPMC11370705 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature