Poly[tris-(2-amino-butan-1-ol)copper(II) [hexa-kis-μ₂-cyanido-κ¹² C:N-tetra-copper(I)] bis-(2-amino-butan-1-olato)aqua-copper(II) monohydrate].

ABSTRACT: The title structure, {[Cu(C₄H₁₁NO)₃][Cu₄(CN)₆]·[Cu(C₄H₁₀NO)₂(H₂O)]·H₂O} _n , is made up of diperiodic honeycomb Cu^ICN networks built from [Cu₄(CN)₆]^2- units, together with two independent Cu^II complexes: six-coord-inate [Cu(CH₃CH₂CH(NH₂)CH₂OH)₃]²⁺ cations, and five-coordinate [Cu(CH₃CH₂CH(NH₂)CH₂O)₂·H₂O] neutral species. The two Cu^II complexes are not covalently bonded to the Cu^ICN networks. Strong O-H⋯O hydrogen bonds link the Cu^II complexes into p

SUBMITTER: Corfield PWR 

PROVIDER: S-EPMC11375604 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature