Transparent porous films with real refractive index close to unity for photonic applications.
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ABSTRACT: Herein, we demonstrate mechanically stable large-area thin films with a purely real refractive index (n) close to 1 in the optical range. At specific wavelengths, it can reach values as small as n = 1.02, the lowest reported for thin solid slabs. These are made of a random network of interwoven spherical silica shells, created by chemical vapour deposition of a thin layer of silica on the surface of randomly packed monodisperse polymer nanoparticles that form a film. Thermal processing of the composites results in highly porous silica-based transparent thin films. We demonstrate the potential of this approach by making novel photonic materials such as strong optical diffusers, built by integrating scattering centers within the ultralow n transparent films, or highly ef
SUBMITTER: Miranda-Munoz JM
PROVIDER: S-EPMC11378018 | biostudies-literature | 2024 Nov
REPOSITORIES: biostudies-literature
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