Tunable SIM properties in a family of 3D anilato-based lanthanide-MOFs.

ABSTRACT: By reacting a 3,6-ditriazolyl-2,5-dihydroxybenzoquinone (H₂trz₂An) anilato linker with Ln^III ions (Ln^III = Dy, Tb, Ho), two different series of polymorphs, formulated as [Ln₂(trz₂An)₃(H₂O)₄] _n ·10H₂O (Dy^III, 1a; Tb^III, 2a, Ho^III, 3a) and [Ln₂(trz₂An)₃(H₂O)₄] _n ·7H₂O (Dy^III, 1b, Tb^III, 2b, Ho^III, 3b) have been obtained. In these series the two Dy^III-coordination networks (1a and 1b) and the Tb^III-coordination polymer (2b) show a Single Ion Magnet (SIM) behavior. 1-3a MOFs show reversible structur

SUBMITTER: Monni N 

PROVIDER: S-EPMC11385371 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature