1D Lead Bromide Hybrids Directed by Complex Cations: Syntheses, Structures, Optical and Photocatalytic Properties.

ABSTRACT: This study presents the synthesis, structural characterization, and evaluation of the photocatalytic performance of two novel one-dimensional (1D) lead(II) bromide hybrids, [Co(2,2'-bpy)₃][Pb₂Br₆CH₃OH] (1) and [Fe(2,2'-bpy)₃][Pb₂Br₆] (2), synthesized via solvothermal reactions. These compounds incorporate transition metal complex cations as structural directors, contributing to the unique photophysical and photocatalytic properties of the resulting materials. Single-crystal X-ray diffraction analysis reveals that both compounds crystallize in monoclinic space groups with distinct 1D lead bromide chain configurations influenced by the nature of the complex cations. Optical property assessments show ba

SUBMITTER: Liu YQ 

PROVIDER: S-EPMC11397344 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature