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A Conductive Dinuclear Cuprous Complex Mimicking the Active Edge Site of the Copper(100)/(111) Plane for Selective Electroreduction of CO₂ to C₂H₄ at Industrial Current Density.

ABSTRACT: Inorganic solids are a kind of important catalysts, and their activities usually come from sparse active sites, which are structurally different from inactive bulk. Therefore, the rational optimization of activity depends on studying these active sites. Copper is a widely used catalyst and is expected to be a promising catalyst for the electroreduction of CO₂ to C₂H₄. Here, we report a conductive dinuclear cuprous complex with a short Cu···Cu contact for the electroreduction of CO₂ to C₂H₄. By using 1H-[1,10]phenanthrolin-2-one and Cu(I) ions, a dinuclear cuprous complex [Cu₂(ophen)₂] (Cuophen) with a remarkable conductivity (3.9 × 10^-4 S m^-1) and a short intramolecular Cu··

SUBMITTER: Heng JM

PROVIDER: S-EPMC11407521 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Dataset Information

A Conductive Dinuclear Cuprous Complex Mimicking the Active Edge Site of the Copper(100)/(111) Plane for Selective Electroreduction of CO₂ to C₂H₄ at Industrial Current Density.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

A Conductive Dinuclear Cuprous Complex Mimicking the Active Edge Site of the Copper(100)/(111) Plane for Selective Electroreduction of CO2 to C2H4 at Industrial Current Density.

OmicsDI is part of the ELIXIR infrastructure

Tweets

A Conductive Dinuclear Cuprous Complex Mimicking the Active Edge Site of the Copper(100)/(111) Plane for Selective Electroreduction of CO₂ to C₂H₄ at Industrial Current Density.