Metal Ion-/Proton-Coupled Electron Transfer (MPCET) on ortho-Quinone.

ABSTRACT: Quinol/quinone equilibria are ubiquitous in nature and find multiple technological applications, most recently in electrical charge storage. Much research has been devoted to proton-coupled electron transfer (PCET) in such systems and to bidentate complexation of ortho-quinol (catechol) ligands with multivalent metal ions but rarely to the interplay of these two reactions. Here, we investigate the impact of a redox-inactive metal ion, as a complexing and charge-compensating agent, on redox processes of catechol in aqueous solutions, that is, in the presence of proton equilibria. We pay separate attention to their thermodynamics and kinetics, which can be regulated by the pH and buffer capacity. As the proton buffer concentration decreases, proton equilibria during catechol PCET are

SUBMITTER: Kumar D 

PROVIDER: S-EPMC11411522 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature