Tetraphenylanthraquinone and Dihydroxybenzene-Tethered Conjugated Microporous Polymer for Enhanced CO₂ Uptake and Supercapacitive Energy Storage.

ABSTRACT: Conjugated microporous polymers (CMPs) feature extended excellent porosity properties and fully conjugated electronic systems, making them highly effective for several uses, including photocatalysis, dye adsorption, CO₂ capture, supercapacitors, and so on. These polymers are known for their high specific surface area and adjustable porosity. To synthesize DHTP-CMPs (specifically TPE-DHTP CMP and Anthra-DHTP CMP) with abundant nitrogen (N) and oxygen (O) adsorption sites and spherical structures, we employed a straightforward Schiff-base [4 + 2] condensation reaction. This involved using 2,5-dihydroxyterephthalaldehyde (DHTP-2CHO) as the primary building block and phenolic OH group source, along with two distinct structures: 4,4',4″,4"'-(ethene-1,1,2,2-tetrayl)tetraaniline (TPE-4

SUBMITTER: Mohamed MG 

PROVIDER: S-EPMC11423306 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature