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An Unprecedented Tridentate-Bridging Coordination Mode of Permanganate Ions: The Synthesis of an Anionic Coordination Polymer-[Co^III(NH₃)₆]_n[(K(κ¹-Cl)₂(μ^2,2',2″-(κ³-O,O',O″-MnO₄)₂)_n^∞]-Containing Potassium Central Ion and Chlorido and Permanganato Ligands.

ABSTRACT: A unique compound (compound 1) with structural features including an unprecedented tridentate-bridging coordination mode of permanganate ions and an eight-coordinated (rhombohedral) κ¹-chlorido and tridentate permanganato ligand in a potassium complex containing coordination polymer (Co^III(NH₃)₆]_n[(K(κ¹-Cl)₂(μ^2,2',2″-(κ³-O,O',O″-MnO₄)₂)_n^∞) with isolated regular octahedral hexamminecobalt(III) cation was synthesized with a yield of >90%. The structure was found to be stabilized by mono and bifurcated N-H∙∙∙Cl and N-H∙∙∙O (bridging and non-bridging) hydrogen bonds. Detailed spectroscopic (IR, far-IR, and Raman) studies and correlation analysis

SUBMITTER: Kotai L

PROVIDER: S-EPMC11433707 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature

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An Unprecedented Tridentate-Bridging Coordination Mode of Permanganate Ions: The Synthesis of an Anionic Coordination Polymer-[Co^III(NH₃)₆]_n[(K(κ¹-Cl)₂(μ^2,2',2″-(κ³-O,O',O″-MnO₄)₂)_n^∞]-Containing Potassium Central Ion and Chlorido and Permanganato Ligands.

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An Unprecedented Tridentate-Bridging Coordination Mode of Permanganate Ions: The Synthesis of an Anionic Coordination Polymer-[CoIII(NH3)6]n[(K(κ1-Cl)2(μ2,2',2″-(κ3-O,O',O″-MnO4)2)n∞]-Containing Potassium Central Ion and Chlorido and Permanganato Ligands.

OmicsDI is part of the ELIXIR infrastructure

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An Unprecedented Tridentate-Bridging Coordination Mode of Permanganate Ions: The Synthesis of an Anionic Coordination Polymer-[Co^III(NH₃)₆]_n[(K(κ¹-Cl)₂(μ^2,2',2″-(κ³-O,O',O″-MnO₄)₂)_n^∞]-Containing Potassium Central Ion and Chlorido and Permanganato Ligands.