Influence of Linear Diamine Counterions on the Self-Assembly of Glycine-, Alanine-, Valine-, and Leucine-Based Amphiphiles.

ABSTRACT: Electrical conductimetry and dynamic light scattering (DLS) were used to investigate the aggregation behaviors of four amino acid-based surfactants (AABSs; undecanoyl-glycine, undecanoyl-l-alanine, undecanoyl-l-valine, undecanoyl-l-leucine) in the presence of five linear diamine counterions (1,2-diaminoethane, 1,3-diaminopropane, 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexane). Electrical conductimetry was used to measure the CMCs for each system, which ranged from 5.1 to 22.5 mM. With respect to counterions, the obtained CMCs decreased with increases in the interamine spacer length; this was attributed to the improved torsional binding flexibility in longer counterions. Strong linear correlations (mean R² = 0.9443) were observed between the CMCs a

SUBMITTER: Alvarez MA 

PROVIDER: S-EPMC11434146 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature