From Methane to Methanol: Pd-iC-CeO₂ Catalysts Engineered for High Selectivity via Mechanochemical Synthesis.

ABSTRACT: In the pursuit of selective conversion of methane directly to methanol in the liquid-phase, a common challenge is the concurrent formation of undesirable liquid oxygenates or combustion byproducts. However, we demonstrate that monometallic Pd-CeO₂ catalysts, modified by carbon, created by a simple mechanochemical synthesis method exhibit 100% selectivity toward methanol at 75 °C, using hydrogen peroxide as oxidizing agent. The solvent free synthesis yields a distinctive Pd-iC-CeO₂ interface, where interfacial carbon (iC) modulates metal-oxide interactions and facilitates tandem methane activation and peroxide decomposition, thus resulting in an exclusive methanol selectivity of 100% with a yield of 117 μmol/g_cat at 75 °C. Notably, solvent interactions of H<

SUBMITTER: Jimenez JD 

PROVIDER: S-EPMC11440493 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature