3D Printing of Thermally Responsive Shape Memory Liquid Crystalline Epoxy Networks.
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ABSTRACT: A two-component liquid crystalline epoxy network (LCEN) with shape memory behavior was developed and evaluated as a candidate material for 3D printing. The cure kinetics of the uncured material and the shape memory properties of the cured LCEN were investigated by using parallel plate rheology and dynamic mechanical analysis, respectively. A commercially available fumed silica additive was introduced to the neat, uncured material to improve the rheological properties for 3D printing. The addition of fumed silica was found to increase the yield stress, shear-thinning behavior, and toughness of the uncured epoxy ink. Polarized light microscopy, differential scanning calorimetry, and wide-angle X-ray scattering measurements between the neat and additive-modified LCEN suggested a reduction in
SUBMITTER: Pekol C
PROVIDER: S-EPMC11447742 | biostudies-literature | 2024 Oct
REPOSITORIES: biostudies-literature
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