Biobased Chemicals from d-Galactose: An Efficient Route to 5-Hydroxymethylfurfural Using a Water/MIBK System in Combination with an HCl/AlCl₃ Catalyst.

ABSTRACT: 5-Hydroxymethylfurfural (HMF) is an attractive building block for biobased chemicals. Typically, ketoses like d-fructose (FRC) are suitable starting materials and give good yields of HMF in a simple aqueous phase process with a Bro̷nsted acid catalyst. With aldoses, such as d-glucose (GLU), much lower yields were reported in the literature. Here, we report an experimental and modeling study on the use of d-galactose (GAL) for HMF synthesis, using a liquid-liquid system (water/MIBK) in combination with an HCl/AlCl₃ catalyst. Experiments were conducted in a batch system with temperatures between 112 and 153 °C, HCl and AlCl₃ concentrations ranging from 0.02 to 0.04 M, and initial GAL concentrations between 0.1 and 1.0 M. The highest HMF yield was 49 mol % obtained for a

SUBMITTER: Martina A 

PROVIDER: S-EPMC11447810 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature