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Structural Diversity and Dimensionality of Three Cu(II)-dpds-C₅O₅ ^2- Coordination Polymers Controlled by the Coordination Sphere of Cu(II) Centers and the Coordination Modes of C₅O₅ ^2- (dpds = 4,4'-Dipyridyldisulfide).

ABSTRACT: Three supramolecular architectures, [Cu₂(dpds)₂(C₅O₅)₂(H₂O)₄]·3H₂O (1), [Cu(dpds)(C₅O₅)]·3H₂O (2), and [Cu₂(dpds)₂(C₅O₅)₂]·9H₂O·C₂H₅OH (3) (dpds = 4,4'-dipyridyldisulfide and C₅O₅ ^2- (croconate) = dianion of 4,5-dihydroxycyclopent-4-ene-1,2,3-trione), have been synthesized and structurally characterized. Compound 1 contains two crystallographically independent Cu(II) ions, which are both distorted octahedral geometry with elongation along the croconate- and H₂O-bound axial positions and bonded with two N atoms of

SUBMITTER: Wang CC

PROVIDER: S-EPMC11447864 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature

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Dataset Information

Structural Diversity and Dimensionality of Three Cu(II)-dpds-C₅O₅ ^2- Coordination Polymers Controlled by the Coordination Sphere of Cu(II) Centers and the Coordination Modes of C₅O₅ ^2- (dpds = 4,4'-Dipyridyldisulfide).

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Dataset Information

Structural Diversity and Dimensionality of Three Cu(II)-dpds-C5O5 2- Coordination Polymers Controlled by the Coordination Sphere of Cu(II) Centers and the Coordination Modes of C5O5 2- (dpds = 4,4'-Dipyridyldisulfide).

OmicsDI is part of the ELIXIR infrastructure

Tweets

Structural Diversity and Dimensionality of Three Cu(II)-dpds-C₅O₅ ^2- Coordination Polymers Controlled by the Coordination Sphere of Cu(II) Centers and the Coordination Modes of C₅O₅ ^2- (dpds = 4,4'-Dipyridyldisulfide).