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Δ-Bis[(S)-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolato-κ² N,O ¹](1,10-phenanthroline-κ² N,N')ruthenium(III) hexa-fluorido-phosphate.

ABSTRACT: The title compound, [Ru(C₁₂H₁₄NO₂)₂(C₁₂H₈N₂)]PF₆ crystallizes in the tetra-gonal Sohnke space group P4₁2₁2. The two bidentate chiral salicyloxazoline ligands and the phenanthroline co-ligand coordinate to the central Ru^III atom through N,O and N,N atom pairs to form bite angles of 89.76 (15) and 79.0 (2)°, respectively. The octa-hedral coordination of the bidentate ligands leads to a propeller-like shape, which induces metal-centered chirality onto the complex, with a right-handed (Δ) absolute configuration [the Flack parameter value is -0.003 (14)]. Both the complex cation and the disordered PF₆ ^- counter-anion are located on twofold rotatio

SUBMITTER: Kelani MT

PROVIDER: S-EPMC11451036 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature

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Dataset Information

Δ-Bis[(S)-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolato-κ² N,O ¹](1,10-phenanthroline-κ² N,N')ruthenium(III) hexa-fluorido-phosphate.

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Δ-Bis[(S)-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolato-κ2 N,O 1](1,10-phenanthroline-κ2 N,N')ruthenium(III) hexa-fluorido-phosphate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Δ-Bis[(S)-2-(4-isopropyl-4,5-di-hydro-oxazol-2-yl)phenolato-κ² N,O ¹](1,10-phenanthroline-κ² N,N')ruthenium(III) hexa-fluorido-phosphate.