CCC-NHC Au(iii) pincer complexes as a reliable platform for isolating elusive species.

ABSTRACT: The reactivity of unprecedented CCC-NHC Au(iii) pincer complexes has been investigated, employing a novel methodology for their preparation. Notably, this marks the inaugural case of CCC-NHC Au(iii) pincer complexes with a central aryl moiety where the two arms of the pincer ligand consist of N-heterocyclic carbenes (NHC). The stability conferred by the CCC-NHC ligand facilitated the isolation of elusive Au(iii) species, encompassing Au(iii)-formate, Au(iii)-F, Au(iii)-Me, and Au(iii)-alkynyl. Our study also unveiled the elusive Au(iii)-H species, offering valuable insights into its formation, stability, and reactivity. While the CCC-NHC Au(iii)-H complex remains stable at room temperature, its decomposition becomes conspicuous at elevated temperatures (>60 °C), exhibiting a more pronounce

SUBMITTER: Valdes H 

PROVIDER: S-EPMC11459386 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature