Constructing a supercapacitor-memristor through non-linear ion transport in MOF nanochannels.

ABSTRACT: The coexistence and coupling of capacitive and memristive effects have been an important subject of scientific interest. While the capacitive effect in memristors has been extensively studied, the reciprocal scenario of the memristive effect in capacitors remains unexplored. In this study, we introduce a supercapacitor-memristor (CAPistor) concept, which is constructed by leveraging non-linear ion transport within the pores of a metal-organic framework zeolitic-imidazolate framework (ZIF-7). Within the nanochannels of the ZIF-7 electrode in an aqueous pseudocapacitor, the anionic species (OH^-) of the electrolyte can be enriched and dissipated in different voltage regimes. This difference leads to a hysteresis effect in ion conductivity, constituting a memristive behavior in the

SUBMITTER: Tang P 

PROVIDER: S-EPMC11462086 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature