Fluorinated Arylarsonate-Containing Polyoxomolybdates: pH-Dependent Formation of Mo₆ vs Mo₁₂ Species and Their Solution Properties.

ABSTRACT: We report on the synthesis and structural characterization of six novel arylarsonate-containing polyoxomolybdates with fluorinated-functionalities in the para position of the phenyl ring. The reaction of the various arylarsonic acids, RAsO₃H₂ [R = 4-F-C₆H₄ (H₂L_F), 4-F₃C-C₆H₄ (H₂L_CF3), 4-F₃CO-C₆H₄ (H₂L_OCF3)] with Na₂MoO₄·2H₂O in aqueous pH 3 solution resulted in the heteropoly-6-molybdates [{(4-F-C₆H₄)As}₂Mo₆O₂₄(H₂O)]^4- (1), [{(4-F₃C-C

SUBMITTER: Pal A 

PROVIDER: S-EPMC11462504 | biostudies-literature | 2024 Oct

REPOSITORIES: biostudies-literature