Engineering spin-dependent catalysts: chiral covalent organic frameworks with tunable electroactivity for electrochemical oxygen evolution.

ABSTRACT: The chiral-induced spin selectivity (CISS) effect offers promising prospects for spintronics, yet designing chiral materials that enable efficient spin-polarized electron transport remains challenging. Here, we report the utility of covalent organic frameworks (COFs) in manipulating electron spin for spin-dependent catalysis via CISS. This enables us to design and synthesize three three-dimensional chiral COFs (CCOFs) with tunable electroactivity and spin-electron conductivity through imine condensations of enantiopure 1,1'-binaphthol-derived tetraaldehyde and tetraamines derived from 1,4-benzenediamine, pyrene, or tetrathiafulvalene skeletons. The CISS effect of CCOFs is verified by magnetic conductive atomic force microscopy. Compared with their achiral analogs, these CCOFs serve as effi

SUBMITTER: Li Z 

PROVIDER: S-EPMC11467994 | biostudies-literature | 2024 Sep

REPOSITORIES: biostudies-literature