Stabilizing γ-MgH₂ at Nanotwins in Mechanically Constrained Nanoparticles.

ABSTRACT: Reversible hydrogen uptake and the metal/dielectric transition make the Mg/MgH₂ system a prime candidate for solid-state hydrogen storage and dynamic plasmonics. However, high dehydrogenation temperatures and slow dehydrogenation hamper broad applicability. One promising strategy to improve dehydrogenation is the formation of metastable γ-MgH₂ . A nanoparticle (NP) design, where γ-MgH₂ forms intrinsically during hydrogenation is presented and a formation mechanism based on transmission electron microscopy results is proposed. Volume expansion during hydrogenation causes compressive stress within the confined, anisotropic NPs, leading to plastic deformation of β-MgH₂ via (301)_β twinning. It is proposed that these twins nucleate γ-MgH

SUBMITTER: Kammerer JA 

PROVIDER: S-EPMC11468506 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature