Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors.

ABSTRACT: In this work, the covalent attachment of an amine functionalized metal-organic framework (UiO-66-NH₂  = Zr₆ O₄ (OH)₄ (bdc-NH₂ )₆ ; bdc-NH₂  = 2-amino-1,4-benzenedicarboxylate) (UiO-Universitetet i Oslo) to the basal-plane of carboxylate functionalized graphene (graphene acid = GA) via amide bonds is reported. The resultant GA@UiO-66-NH₂ hybrid displayed a large specific surface area, hierarchical pores and an interconnected conductive network. The electrochemical characterizations demonstrated that the hybrid GA@UiO-66-NH₂ acts as an effective charge storing material with a capacitance of up to 651 F g^-1 , significantly higher than traditional graphene-based materials. The results

SUBMITTER: Jayaramulu K 

PROVIDER: S-EPMC11468759 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature