Tetrafluoroborate-Induced Reduction in Defect Density in Hybrid Perovskites through Halide Management.

ABSTRACT: Hybrid-perovskite-based optoelectronic devices are demonstrating unprecedented growth in performance, and defect passivation approaches are highly promising routes to further improve properties. Here, the effect of the molecular ion BF₄ ^- , introduced via methylammonium tetrafluoroborate (MABF₄ ) in a surface treatment for MAPbI₃ perovskite, is reported. Optical spectroscopy characterization shows that the introduction of tetrafluoroborate leads to reduced non-radiative charge-carrier recombination with a reduction in first-order recombination rate from 6.5 × 10⁶ to 2.5 × 10⁵ s^-1 in BF₄ ^- -treated samples, and a consequent increase in photoluminescence quantum yield by an order of magnitude (

SUBMITTER: Nagane S 

PROVIDER: S-EPMC11468984 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature